The shooter was her ex-husband, who later killed himself inside a townhouse a few miles away, police said. Authorities called the incident a murder-suicide.
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The woman was shot at about 12:30 p.m. at the store located at 13460 South Route 59. She was taken to Bolingbrook Hospital, where she was pronounced dead.
Shortly afterward, police responded to a well-being check at a home on Walnut Circle a few miles away. As they approached, they heard a gunshot. The man was found inside a vehicle in the townhouse garage.
"As our officers were approaching the residence, they heard a shot ring out. Our officers retreated and set up a perimeter around the house. We called in additional assistance from Joliet and many other surrounding communities," said Chief John Konopek, of the Plainfield Police Department.
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Neighbor Nick Vandenbroucke captured cellphone video of a Joliet SWAT vehicle tear down the garage door of the townhouse.