The incident happened earlier this month in the 600 block of South Independence Boulevard, police said.
The suspects pulled up to the gas station in a black Honda Accord.
They can then be seen confronting the victim in his car, and they fire a weapon during a struggle.
SEE ALSO | Woman carjacked at gunpoint on South Side, Chicago police say
Their carjacking attempt was not successful, but they did get away.
Chicago police continue to investigate.
INTERACTIVE SAFETY TRACKER Track crime and safety in your neighborhood