The crash happened at about 2:38 a.m. on the outbound Stevenson Expressway at Pulaski Road near Archer Heights.
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Chicago fire officials and police said the truck was stopped at another accident scene when it was hit. Four people, the SUV's driver and passengers, were transported to a local hospital, where the driver was pronounced dead.
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Officials said no firefighters were hurt in the crash. Further information was not immediately available.